It's worth noting that this is a standard method of proving that a value is transcendental -- just show that it has better rational approximations than any algebraic number can have.
At least, that's my understanding of where things stand, but I'm not an expert. Do you have counterexamples?
(But to clarify: When I said "proving that a value is transcendental", I was thinking of numbers specifically constructed for that purpose, not of other numbers more generally. 100% of transcendental numbers have irrationally measure 2.)