This is interesting! My impression was that SML/NJ was the de facto "standard" Standard ML implementation (maybe analogous to SBCL in the Lisp world), and (FWIW) Gemini agrees, describing it as "the oldest and most widely used". So I'm surprised to see someone stick it in the rear behind Poly/ML and MLton.
I don't really know what to make of that, except that I guess there's a surprisingly vibrant SML ecosystem and don't listen to any one person (myself included) about it: try them all and see which SML implementation is right for you :)
I'm surprised Gemini says SML/NJ its the most widely used. I've been an active Standard ML user for close to 30 years, and while that was certainly true for the first half of that time, I found most projects around me drifted to defaulting to want to compile with mlton or polyml. SML/NJ's heap2exec was a bit clunky compared to the others. It's great that they're slowly moving it over to LLVM.